First and foremost, D0VE heads and a 0.030" overbored 545 with flat top pistons will exceed 13:1 compression ratio, and so pump gas is completely out of the question.
Secondly, D0VE heads can make for a really great 5500 rpm jet boat engine, for example, but they must be properly ported in order to get really good results. Conversely, without any porting your engine will wheeze above 4500 rpm.
LO