Ok, I'm assuming this is a K1500, 6 lug setup right?
First off, the reason I said don't bleed it or replace the master cylinder is because we've got a problem of the rear brakes working too good. Hydraulic parts/systems cannot wear out and work better than they did before. Not possible. You can't make too much pressure with a bad master cylinder. I'd ask how the pedal feels, but it's perfectly normal in these trucks to be able to push to pedal to the floor at idle, so that's not a good indicator.
The problem is most likely the rear shoes themselves or more specifically, how and where the shoe contacts the drum.
Make sure that the leading and trailing shoes are in the correct locations....the shoe with the shortest/smallest lining goes towards the front of the vehicle. If the linings on all 4 shoes are same length, see if they are positioned differently on the steel, and see if front shoe has the leading edge of the lining higher or lower than the rear shoe.
Modern brake shoes are a crap shoot because the days of measuring the drum and then arcing the shoes in the repair shop on a cam-grinder to properly fit the drum are long gone...we're dealing with one size fits all shoe arcs, that are usually not exactly right.
The most important factor in a drum brake system is where top of the leading shoe lining is located relative to the wheel cylinder and lower anchor point. The farther toward the bottom you move the top of the lining, the more effective and "self actuating" they become, becuase you're increasing leverage on the contact point as well as improving the geometry of the system. Conversely, the farther up towards the wheel cylinder you move the top edge of the leading shoe lining, the less aggressive the brake becomes. A lot of the shoe relining plants have gone away and most product lines have been using brand new shoes from mostly China...which is fine, if the factory understands the concept of how brake shoes work, which many don't....many started off making brake pads, where higher mu (friction coefficent) is generally better....with a shoe, this is not the case. Not only do you have to use the correct length lining, bonded to the shoe in the correct location, but also use a material that will work correctly based upon the above two conditions for that specific part number....and lots of these factories haven't been "trained" yet as to how to build shoes correctly.
Pull a drum off and post of picture of the leading shoe, trailing shoe, as well as the whole assembly. I can probably do better after seeing these pictures.
Also, see if you can get a casting number off of a wheel cylinder...I can run that and see if it's got the correct size cylinders on it.